I think if Light and Shadow were added, it would pose a bigger question of how an element is "added" in the first place. Does "adding" just represent when Lion Turtles gave people the ability to lightbend/shadowbend?
If so, I think there are two possibilities: fire, air, water, earth, light, shadow (which would be correct according to lore, seeing as the avatar cycle started with a firebender) or: air, water, earth, fire, light, shadow. The only reason I could see the latter happening is because the show originally began with Aang, an airbender and in away he represents the first avatar since he's the first whose story we (as viewers) see. Looking back, the first does make more sense, but let me know.
The only reason why I think Light should come before Shadow is because that's usually how people refer to it- as in 'light and shadow' rather than 'shadow and light'.
@Zealous Gamer The only reason why I asked was because if Shadow does represent the fantastical idea of Darkness, should it still be called shadow? (granted, 'darkbenders' does sound kind of weird, and 'light and shadow' sound better together)
I also checked out some your other "Just for Fun" threads and they all seem really interesting & well founded! Are you thinking of putting all of it into one larger post, or blog post (not sure thats what they're called but the kind of posts where it's your own page or smt?)